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| Electron microscopy images of the phase boundary between crystalline silicon and amorphous lithiated silicon, revealing its atomic structure. The sharp jumps in stress, composition and atomic structure across the phase boundary play an important role in determining the mechanical damage that results in silicon crystals during the initial charge cycle. |
“This award represents a truly interdisciplinary research effort that brings together solid mechanics, chemistry and materials science,” said Guduru. “The research effort presents an opportunity for Brown and URI researchers to contribute to a technological area of national importance and forge strong collaborations with national labs and industry.”
“This new award contributes to the growing portfolio of engineering research at Brown in the energy and nanoscience fields,” said Dean Larry Larson. “These new fields are changing the way we live in thousands of different ways. Congratulations to all the faculty, post-docs, staff and students involved in these successful efforts.”
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| Electron microscopy images of the phase boundary between crystalline silicon and amorphous lithiated silicon, revealing its atomic structure. The sharp jumps in stress, composition and atomic structure across the phase boundary play an important role in determining the mechanical damage that results in silicon crystals during the initial charge cycle. |
The objective of the reserach funded under the DOE EPSCoR grant is to establish a comprehensive research program at Brown University and University of Rhode Island to develop fundamental and quantitative understanding of degradation mechanisms that limit the performance and cycle life of LIBs; and use the insights gained to help develop materials and architectures with significantly improved performance.
The research program encompasses critical challenges in the three major battery components: anodes, electrolytes and cathodes. Mechanical and chemical degradation of electrodes associated with large volume changes during charging and discharging is a critical factor that limits their capacity and lifetime. However, the degradation mechanisms are not well-understood quantitatively, which is a critical obstacle in developing the next generation of LIBs. The research team will address the fundamental issues of mechanical behavior & performance, controlling electrochemical side-reactions, formation and stability of solid-electrolyte interphase (SEI) layers. Through a combined experimental and computational approach, the team plans to develop the necessary quantitative understanding, which can help make battery materials design a well-controlled, principle-based process with predictable outcomes, in contrast to the largely trial and error based empirical approach being followed currently. The PIs will work with collaborators in national laboratories and battery industry in addressing the relevant problems of highest impact for developing the next generation of higher energy density battery systems.
